Not every app is on the same scale. O2 uses the official United States EPA Air Quality Index, which runs 0 to 500. Some apps and monitors use other scales — a few extend well past 1000 during extreme events, and other countries use entirely different indices — so the same air can read 175 here and a far larger number elsewhere.
O2's readings come from Open-Meteo, built on CAMS, the Copernicus Atmosphere Monitoring Service — a science-grade global model run by the EU's ECMWF. Because it is one consistent method applied everywhere, O2 gives you a comparable 0-to-500 reading anywhere in the country, including places with no monitor nearby.
A single ground monitor can be more precise at its exact spot, but coverage is patchy and scales vary. When two sources disagree, check which scale each one uses before assuming either is wrong.